Have you been adding those image files via the Resources page of the project properties? If not then you should. In that case, remove the files from the Resources folder and then re-add them to the project properties.
You can then get an Image object in code using My.Resources.SomeProperty, where SomeProperty is the name of your resource. That Image object can be assigned to the Image property of a PictureBox.
A point to note is that, each time you use a property of My.Resources, a new object is created. As such, if you intend to use an Image multiple times then it would be preferable to assign it to a variable and reuse it from there. Also, just like any other Image, you should Dispose it once you're done with it.