CC,
You are mixing up design time and run time. You can only use the toolbox at design time. In this case, you can add a second form to your project, add any GUI components you want and then run the application. The startup form can be used to show the second form using the run-time code like...
Here are links that might be helpful:
http://samples.gotdotnet.com/quickstart/aspplus/doc/webservicesintro.aspx
http://support.microsoft.com/default.aspx?scid=KB;EN-US;Q301273&ID=KB;EN-US;Q301273
http://www.dotnetjunkies.com/quickstart/aspplus/doc/writingservices.aspx
I also have a brief...
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